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Research Paper | Applied Chemistry | Morocco | Volume 6 Issue 7, July 2017 | Popularity: 7.2 / 10
DFT Study and Synthesis of New 1, 2, 3-triazoles Obtained by 1, 3-Dipolar Cycloaddition Derived from 5-chloro-1-(prop-2-yn-1-yl)indoline-2, 3-dione
Z. Tribak, M. K. Skalli, O. Senhaji, Y. Kandri Rodi
Abstract: We report in this paper the reaction of 1, 3-Dipolar Cycloaddition between azides and 5-chloro-1- (prop-2-yn-1-yl) indoline-2, 3-dione in order to synthesize new cycloadducts. The configuration of the products obtained was determined by the magnetic resonance of the proton and carbon. A theoretical study was also carried out, based on the DFT-B3LYP calculation method. The results are in agreement with experimental regiochemistry.
Keywords: 5-chloro-1- prop-2-yn-1-yl indoline-2, 3-dione, dipolarophile, 1, 3-Dipolar Cycloaddition, theoretical study, DFT
Edition: Volume 6 Issue 7, July 2017
Pages: 1069 - 1074
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